Lithiosilanes and their application to the synthesis of polysilane dendrimers

Citation
A. Sekiguchi et al., Lithiosilanes and their application to the synthesis of polysilane dendrimers, COORD CH RE, 210, 2000, pp. 11-45
Citations number
137
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
COORDINATION CHEMISTRY REVIEWS
ISSN journal
00108545 → ACNP
Volume
210
Year of publication
2000
Pages
11 - 45
Database
ISI
SICI code
0010-8545(200012)210:<11:LATATT>2.0.ZU;2-X
Abstract
An account is given of the preparation and structural investigations of sil yllithium compounds, including X-ray and NMR data. This review covers the c hemistry of lithiosilanes with alkyl, aryl, functional substituents and lit hiooligosilanes with Si-Si bonds. Application of lithiosilanes for the synt hesis of polysilane dendritic molecules is also described. (C) 2000 Elsevie r Science B.V. All rights reserved.