Cellular solid behaviour of liquid crystal colloids - 1. Phase separation and morphology

We study the phase ordering colloids suspended in a thermotropic nematic li quid crystal below the clearing point T-ni and the resulting aggregated str ucture. Small (150 nm) PMMA particles are dispersed in a classical liquid c rystal matrix, 5CB or MBBA. With the help of confocal microscopy we show th at small colloid particles densely aggregate on thin interfaces surrounding large volumes of clean nematic liquid, thus forming an open cellular struc ture, with the characteristic size of 10-100 mum inversely proportional to the colloid concentration. A simple theoretical model, based on the Landau mean-field treatment, is developed to describe the continuous phase separat ion and the mechanism of cellular structure formation.