Local entropic effects of polymers grafted to soft interfaces

Citation
T. Bickel et al., Local entropic effects of polymers grafted to soft interfaces, EUR PHY J E, 4(1), 2001, pp. 33-43
Citations number
44
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
EUROPEAN PHYSICAL JOURNAL E
ISSN journal
12928941 → ACNP
Volume
4
Issue
1
Year of publication
2001
Pages
33 - 43
Database
ISI
SICI code
1292-8941(200101)4:1<33:LEEOPG>2.0.ZU;2-W
Abstract
In this paper, we study the equilibrium properties of polymer chains end-te thered to a fluid membrane. The loss of conformational entropy of the polym er results in an inhomogeneous pressure field that we calculate for Gaussia n chains. We estimate the effects of excluded volume through a relation bet ween pressure and concentration. Under the polymer pressure, a soft surface will deform. We calculate the deformation profile for a fluid membrane and show that close to the grafting point, this profile assumes a cone-like sh ape, independently of the boundary conditions. Interactions between differe nt polymers are also mediated by the membrane deformation. This pair-additi ve potential is attractive for chains grafted on the same side of the membr ane and repulsive otherwise.