The embanked floodplains of the lower Rhine river in the Netherlands contai
n large amounts of heavy metals, which is a result of many years of deposit
ion of contaminated overbank sediments. The metal pollution varies greatly
between the various floodplain sections as well as in vertical direction wi
thin the floodplain soil profiles. The present contribution describes the k
ey processes producing the spatial variability of the metal pollution in fl
oodplain soils: (1) spatial patterns of the concentrations and deposition o
f Cd, Cu, Pb and Zn during a single flood, which have been determined from
samples collected after a high-magnitude flood event; (2) the pollution tre
nds of the lower Rhine over the past 150 years, which were reconstructed on
the basis of metal concentrations in sediments from small ponds within the
floodplain area. During the flood the largest metal depositions (0.03 g/m(
2) Cd, 0.7 g/m(2) Cu, 1.1 g/m(2) Pb and 5.0 g/m(2) Zn for the Rhine) occurr
ed along the natural levees, decreasing to about one third of these values
at larger distance from the river. Deposition of heavy metals occurred sinc
e the end of the nineteenth century. Periods of maximum pollution occurred
in the 1930s and 1960s, when Cu, Pb and Zn concentrations were about 6-10 t
imes as high as background values.
The resulting metal distribution in the floodplain soil profiles is illustr
ated by means of typical examples. Maximum metal concentrations in floodpla
in soils vary from 30 to 130 mg/kg for Cu, from 70 to 490 mg/kg for Pb, and
from 170 to 1450 mg/kg for Zn. The lowest metal pollution is found in the
distal parts of floodplain sections with low flooding frequencies, where av
erage sedimentation rates have been less than about 5 mm/a. The largest met
al accumulations occur in low-lying floodplain sections where average sedim
entation rates have been more than 10 mm/a.