ELECTROACTIVE POLYMER-FILMS OF SILVER COMPLEXES WITH INTERTWINED AND INTERLOCKED LIGANDS - THE AG-I-AG-0 REDOX COUPLE AS A TOPOLOGICAL PROBE

Authors
BILLON M DIVISIABLOHORN B KERN JM SAUVAGE JP
Citation
M. Billon et al., ELECTROACTIVE POLYMER-FILMS OF SILVER COMPLEXES WITH INTERTWINED AND INTERLOCKED LIGANDS - THE AG-I-AG-0 REDOX COUPLE AS A TOPOLOGICAL PROBE, Journal of materials chemistry, 7(7), 1997, pp. 1169-1173
Citations number
26
Categorie Soggetti
Chemistry Physical","Material Science
Journal title
Journal of materials chemistry → ACNP
ISSN journal
09599428
Volume
7
Issue
7
Year of publication
1997
Pages
1169 - 1173
Database
ISI
SICI code
0959-9428(1997)7:7<1169:EPOSCW>2.0.ZU;2-2
Abstract
The electrochemical properties of bis(2,9-diaryl-1,10-phenanthroline)s ilver complexes are reported. The redox potentials of the coordinated metal centre are strongly dependent on the topology of the organic bac kbone surrounding the metal centre and its set of ligands. This partic ular property can be used for the evaluation of the topological charac teristics of different polypyrrole matrices built around entwined 2,9- diaryl-1,10-phenanthroline moieties.