Crystal structure and redox behavior of a novel siderophore model system: A trihydroxamato-Iron(III) complex with intra- and interstrand hydrogen bonding networks

Authors
Matsumoto, K Ozawa, T Jitsukawa, K Einaga, H Masuda, H
Citation
K. Matsumoto et al., Crystal structure and redox behavior of a novel siderophore model system: A trihydroxamato-Iron(III) complex with intra- and interstrand hydrogen bonding networks, INORG CHEM, 40(2), 2001, pp. 190
Citations number
9
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY
ISSN journal
00201669 → ACNP
Volume
40
Issue
2
Year of publication
2001
Database
ISI
SICI code
0020-1669(20010115)40:2<190:CSARBO>2.0.ZU;2-O
Abstract
An iron(III) complex of a novel tripodal tris-hydroxamate, tris [2-{(N-acet yl-N-hydroxy)glycylamino}ethyl]amine (TAGE), was synthesized as a sideropho re model. Its X-ray structure revealed that intra- and interstrand hydrogen bonding networks cause an increase in the iron redox potential.