Mono- and dinuclear zinc complexes derived from unsymmetric binucleating ligands: Synthesis, characterization, and formation of tetranuclear arrays

Authors
Erxleben, A
Citation
A. Erxleben, Mono- and dinuclear zinc complexes derived from unsymmetric binucleating ligands: Synthesis, characterization, and formation of tetranuclear arrays, INORG CHEM, 40(2), 2001, pp. 208-213
Citations number
31
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY
ISSN journal
00201669 → ACNP
Volume
40
Issue
2
Year of publication
2001
Pages
208 - 213
Database
ISI
SICI code
0020-1669(20010115)40:2<208:MADZCD>2.0.ZU;2-H
Abstract
An iron(III) complex of a novel tripodal tris-hydroxamate, tris[2-{(N-acety l-N-hydroxy)glycylamino}ethyl]amine (TAGE), was synthesized as a siderophor e model. Its X-ray structure revealed that intra- and interstrand hydrogen bonding networks cause an increase in the iron redox potential.