Synthesis and crystal structure of trans-nitrosoaquatetraammineruthenium(II) sulphate hydrosulphate, [Ru(NO) (NH3)(4)(H2O)](SO4)( HSO4)

Authors
Emel'yanov, VA Virovets, AV Baidina, IA Gromilov, SA Belyaev, AV
Citation
Va. Emel'Yanov et al., Synthesis and crystal structure of trans-nitrosoaquatetraammineruthenium(II) sulphate hydrosulphate, [Ru(NO) (NH3)(4)(H2O)](SO4)( HSO4), INORG CH C, 4(1), 2001, pp. 33-35
Citations number
16
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY COMMUNICATIONS
ISSN journal
13877003 → ACNP
Volume
4
Issue
1
Year of publication
2001
Pages
33 - 35
Database
ISI
SICI code
1387-7003(200101)4:1<33:SACSOT>2.0.ZU;2-V
Abstract
The reaction between [RuNO(NH3)(4)OH]Cl-2 and an excess of 2 M H2SO4 leads to the protonation of the starting complex and crystallisation of the title complex with sulphate and hydrosulphate anions. The crystal structure of t he product has been determined. The linear nitroso group and water molecule are coordinated in trans positions. (C) 2001 Elsevier Science B.V. All rig hts reserved.