2D structure with rectangular grids woven by coordination chains and pseudo-metal wires

Authors
Zhang, HX Kang, BS Deng, LR Ren, C Su, CY Chen, ZN
Citation
Hx. Zhang et al., 2D structure with rectangular grids woven by coordination chains and pseudo-metal wires, INORG CH C, 4(1), 2001, pp. 41-44
Citations number
29
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY COMMUNICATIONS
ISSN journal
13877003 → ACNP
Volume
4
Issue
1
Year of publication
2001
Pages
41 - 44
Database
ISI
SICI code
1387-7003(200101)4:1<41:2SWRGW>2.0.ZU;2-L
Abstract
A heterometallic assembly, [{Cd(en)(2)Ag(CN)(2)} {Ag(CN)(2)}](n), has been synthesized and structurally characterized. The 2D layered structure is con structed by interweaving the coordination chains of {Cd(en)(2)Ag(CN)(2)}(+) containing Cd-N equivalent toC-Ag linkage with the pseudo-metal wires form ed by the anions [Ag(CN)(2)](-) and Ag(I) of the chains through Ag-Ag inter actions. (C) 2001 Elsevier Science B.V. All rights reserved.