Five co-ordination at platinum(II) in a water soluble tertiary phosphine complex: crystal structure of [Pt(PTA)(3)(I)(2)]center dot CH3OH

Authors
Otto, S Roodt, A
Citation
S. Otto et A. Roodt, Five co-ordination at platinum(II) in a water soluble tertiary phosphine complex: crystal structure of [Pt(PTA)(3)(I)(2)]center dot CH3OH, INORG CH C, 4(1), 2001, pp. 49-52
Citations number
20
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY COMMUNICATIONS
ISSN journal
13877003 → ACNP
Volume
4
Issue
1
Year of publication
2001
Pages
49 - 52
Database
ISI
SICI code
1387-7003(200101)4:1<49:FCAPIA>2.0.ZU;2-T
Abstract
A five co-ordinate platinum(II) complex containing the water soluble 1,3,5- triaza-7-phosphaadamantane ligand (PTA) [Pt(PTA)(3)(I)(2)] (1), was charact erised in the solid state and aqueous solution. A re-calculation of the Tol man cone angle for the PTA ligand, as well as preliminary equilibrium const ants for the formation of 1, is given. (C) 2001 Published by Elsevier Scien ce B.V. All rights reserved.