Equilibrium conversion degrees in direct synthesis of dimethyl ether from CO and H-2

Citation
M. Grzesik et al., Equilibrium conversion degrees in direct synthesis of dimethyl ether from CO and H-2, INZ CHEM PR, 21(4), 2000, pp. 725-732
Citations number
10
Categorie Soggetti
Chemical Engineering
Journal title
INZYNIERIA CHEMICZNA I PROCESOWA
ISSN journal
02086425 → ACNP
Volume
21
Issue
4
Year of publication
2000
Pages
725 - 732
Database
ISI
SICI code
0208-6425(2000)21:4<725:ECDIDS>2.0.ZU;2-G
Abstract
The influence of temperature, pressure and initial molar ratio of substrate s on the equilibrium conversion degrees in direct synthesis of dimethyl eth er (DME) from CO and H-2 has been established. The significant influence of the temperature on the equilibrium content of the product has been found. Modelling results have shown that the one-step synthesis of DME from CO and H-2 in higher pressures and relatively lower temperatures (T < 550 K) is b eneficial because of the high selectivity and yield of the main process pro duct.