Thermodynamics of the selective hydrogenation of carbon monoxide to higheraliphatic alcohols

Citation
M. Grzesik et al., Thermodynamics of the selective hydrogenation of carbon monoxide to higheraliphatic alcohols, INZ CHEM PR, 21(4), 2000, pp. 733-740
Citations number
10
Categorie Soggetti
Chemical Engineering
Journal title
INZYNIERIA CHEMICZNA I PROCESOWA
ISSN journal
02086425 → ACNP
Volume
21
Issue
4
Year of publication
2000
Pages
733 - 740
Database
ISI
SICI code
0208-6425(2000)21:4<733:TOTSHO>2.0.ZU;2-0
Abstract
The effect of initial concentrations of substrates, temperature and pressur e on the conversion degrees of carbon oxide to aliphatic alcohols C-1-C-4 a t the chemical equilibrium state was described. From the results obtained i t can be seen that propyl and butyl alcohols are the main products at the c hemical equilibrium, with butanol dominating, whereas methyl and ethyl alco hols exist only in trace concentrations.