[PtCl3(C2H4)](-)[AmH](+) complexes containing chiral secondary amines: Useas chiral derivatizing agents for the enantiodiscrimination of unsaturatedcompounds by Pt-195 NMR spectroscopy and NMR stereochemical investigation

Authors
Uccello-Barretta, G Bernardini, R Balzano, F Salvadori, P
Citation
G. Uccello-barretta et al., [PtCl3(C2H4)](-)[AmH](+) complexes containing chiral secondary amines: Useas chiral derivatizing agents for the enantiodiscrimination of unsaturatedcompounds by Pt-195 NMR spectroscopy and NMR stereochemical investigation, J ORG CHEM, 66(1), 2001, pp. 123-129
Citations number
31
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
JOURNAL OF ORGANIC CHEMISTRY
ISSN journal
00223263 → ACNP
Volume
66
Issue
1
Year of publication
2001
Pages
123 - 129
Database
ISI
SICI code
0022-3263(20010112)66:1<123:[CCCSA>2.0.ZU;2-I
Abstract
Ionic complexes [PtCl3(C2H4)](-)[AmH](+), containing chiral secondary amine s, constitute a versatile class of chiral derivatizing agents (CDAs) for th e enantiomeric purity determination of chiral unsaturated compounds via Pt- 195 NMR spectroscopy The NMR conformational analysis allows us to search fo r the stereochemical basis of their enhanced versatility.