B. Nizamov et Pj. Dagdigian, Collisional quenching and vibrational energy transfer in the A(2)Sigma(+) electronic state of the CF radical, J PHYS CH A, 105(1), 2001, pp. 29-33
Electronic quenching of the nu' = 0 and 1 vibrational levels and nu' = 1 --
> nu' = 0 vibrational energy transfer has been studied at room temperature
for the A(2)Sigma (+) electronic state of the CF radical. The colliders inv
estigated were He, Ar, H-2, N-2, CH4, O-2, CO, C3H8, and CF4. Room-temperat
ure thermal rate constants were determined. With the exception of CF4, the
quenching rate constants were significant for all molecular colliders. Vibr
ational energy transfer within the A(2)Sigma (+) state was observed only fo
r the CH4 collision partner.