MOLYBDENUM(II)-CATALYZED ALLYLIC SUBSTITUTION

Authors
MALKOV AV BAXENDALE I MANSFIELD DJ KOCOVSKY P
Citation
Av. Malkov et al., MOLYBDENUM(II)-CATALYZED ALLYLIC SUBSTITUTION, Tetrahedron letters, 38(27), 1997, pp. 4895-4898
Citations number
36
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
38
Issue
27
Year of publication
1997
Pages
4895 - 4898
Database
ISI
SICI code
0040-4039(1997)38:27<4895:MAS>2.0.ZU;2-F
Abstract
The new Mo(II) triflate complex 5 has been found to catalzye the C-C b ond forming allylic substitution with silyl enol ethers derived from b eta-dicarbonyls (e.g., 6 + 12 --> 14) and from simple ketones (e.g., 6 + 13 --> 16) as nuclephiles. (C) 1997 Elsevier Science Ltd.