Chiral steroidal phosphines: Synthesis and platinum complexes

Authors
Skoda-Foldes, R Banffy, L Horvath, J Tuba, Z Kollar, L
Citation
R. Skoda-foldes et al., Chiral steroidal phosphines: Synthesis and platinum complexes, MONATS CHEM, 131(12), 2000, pp. 1363-1369
Citations number
18
Categorie Soggetti
Chemistry
Journal title
MONATSHEFTE FUR CHEMIE
ISSN journal
00269247 → ACNP
Volume
131
Issue
12
Year of publication
2000
Pages
1363 - 1369
Database
ISI
SICI code
0026-9247(200012)131:12<1363:CSPSAP>2.0.ZU;2-0
Abstract
The synthesis of novel 3 - and 17-diphenylphosphino-androstane derivatives via homogeneous catalytic P-C coupling is described. The products were char acterized by H-1 and P-31 NMR measurements. According to the NMR investigat ion of the PtCl2P2-type complexes, the steroidal phosphines are trans-coord inated with respect to the Pt-centre exclusively.