The Cu(OTf)(2)- and Yb(OTf)(3)-catalyzed Claisen rearrangement of 2-alkoxycarbonyl-substituted allyl vinyl ethers

Citation
M. Hiersemann et L. Abraham, The Cu(OTf)(2)- and Yb(OTf)(3)-catalyzed Claisen rearrangement of 2-alkoxycarbonyl-substituted allyl vinyl ethers, ORG LETT, 3(1), 2001, pp. 49-52
Citations number
19
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANIC LETTERS
ISSN journal
15237060 → ACNP
Volume
3
Issue
1
Year of publication
2001
Pages
49 - 52
Database
ISI
SICI code
1523-7060(20010111)3:1<49:TCAYCR>2.0.ZU;2-D
Abstract
[GRAPHICS] The Cu(OTf)(2)- and Yb(OTf)(3)-catalyzed Claisen rearrangement of 2-alkoxyc arbonyl-substituted allyl vinyl ethers has been developed. Reactivity and s tereoselectivity strongly depend on the substrate structure.