Modified spontaneous emission spectra of laser dye in inverse opal photonic crystals - art. no. 011801

We have observed strongly modified spontaneous-emission spectra from laser dye in photonic crystals made of inverse opals in titania (TiO2). We identi fy stop bands with large relative widths of 15%, comparable to the dyes' em ission spectrum, and 75% attenuation of the emission strength. For a wide r ange of angles, two stop bands are simultaneously manifested; their angle-d ependent frequencies display an avoided crossing that is corroborated by re flectivity experiments. The edges of the stop bands agree well with band-st ructure calculations, but differ from simple Bragg diffraction as a result of multiple wave coupling. The strongly reduced dispersion of the Bloch mod es likely causes a significant change in the density of states.