THE STRUCTURE AND PHOTOCHEMICAL PROPERTIES OF NOVEL FULGIDES OF INDOLINE SERIES WITH AN ADAMANTYLIDENE FRAGMENT

Authors
METELITSA AV KNYAZHANSKY MI MEDYANTSEVA EA LIASHIK OT ALDOSHIN SM MINKIN VI
Citation
Av. Metelitsa et al., THE STRUCTURE AND PHOTOCHEMICAL PROPERTIES OF NOVEL FULGIDES OF INDOLINE SERIES WITH AN ADAMANTYLIDENE FRAGMENT, Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals, 297, 1997, pp. 93-98
Citations number
11
Categorie Soggetti
Crystallography
Journal title
Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals → ACNP
ISSN journal
1058725X
Volume
297
Year of publication
1997
Pages
93 - 98
Database
ISI
SICI code
1058-725X(1997)297:<93:TSAPPO>2.0.ZU;2-X
Abstract
Two novel fulgides of the indoline series with an adamantylidene fragm ent have been synthesized and their structure and photochemical proper ties studied. Whereas mantylidene-(1'-methyl-3'-indolylmethylene)succi nc anhydride(I) possesses Z-configuration, its homologue, containing a methyl group at the double bond (II), has E-configuration about the C =C bond. The presence of the bulky adamantylidene groups in I and II r esults in lowering of the photocoloration efficiency compared to respe ctive isopropylidene derivatives.