THE SEARCH AND INVESTIGATION OF THE NOVEL PHOTO-THERMOCHROMIC AND LUMINESCENT FLEXIBLE STRUCTURES WITH INTRAMOLECULAR PROTON-TRANSFER

Authors
KNYAZHANSKY MI MAKAROVA NI METELITSA AV SHIF AI PICHKO VP IVAKHNENKO EP
Citation
Mi. Knyazhansky et al., THE SEARCH AND INVESTIGATION OF THE NOVEL PHOTO-THERMOCHROMIC AND LUMINESCENT FLEXIBLE STRUCTURES WITH INTRAMOLECULAR PROTON-TRANSFER, Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals, 297, 1997, pp. 391-396
Citations number
5
Categorie Soggetti
Crystallography
Journal title
Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals → ACNP
ISSN journal
1058725X
Volume
297
Year of publication
1997
Pages
391 - 396
Database
ISI
SICI code
1058-725X(1997)297:<391:TSAIOT>2.0.ZU;2-U
Abstract
Comparative findings of the experimental and quantum-chemical studies of the structures including Intramolecular H-Bond ((OHN)-N-... or (NHN )-N-...) with the endocyclic (A) and exocyclic (B) nitrogen atom have been obtained. The photochromic properties are shown only in the struc tures of B-type favorable for the diabatic formation of the metastable photocolored structure. The molecules of the A-type reveal the thermo chromism and/or fluorescence with the Anomalous Stokes Shift.