Enantioselective aldol reaction of trimethoxysilyl enol ethers with aldehydes catalyzed by p-Tol-BINAP center dot AgF complex

Authors
Yanagisawa, A Nakatsuka, Y Asakawa, K Kageyama, H Yamamoto, H
Citation
A. Yanagisawa et al., Enantioselective aldol reaction of trimethoxysilyl enol ethers with aldehydes catalyzed by p-Tol-BINAP center dot AgF complex, SYNLETT, (1), 2001, pp. 69-72
Citations number
33
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
SYNLETT
ISSN journal
09365214 → ACNP
Issue
1
Year of publication
2001
Pages
69 - 72
Database
ISI
SICI code
0936-5214(200101):1<69:EAROTE>2.0.ZU;2-M
Abstract
New catalytic asymmetric Mukaiyama-type aldol reaction using trimethoxysily l enol ethers was achieved using-p-Tol-BI-NAP.AgF complex as a catalyst. Hi gh syn- and enantioselectivities were obtained both from the E- and Z-silyl enol ethers.