It was found that the dynamic current-voltage (I-U) characteristics of the
n-type porous-silicon-based structures upon prolonged room-temperature stor
age exhibit negative differential conductivity. Exposure of the samples to
a vapor of polar molecules led to the development of self-excited oscillati
ons both during the I-U measurements and in the course of reverse current r
elaxation in the structure studied. The observed effects are explained by t
he formation of deep surface energy levels and their charging by an electri
c current passing upon exposure to the atmosphere containing polar molecule
s. (C) 2000 MAIK "Nauka/Interperiodica".