Reactions of (R-P)- and (S-P)-tert-butylphenylphosphinobromidates and tert-butylphenylthionophosphinochloridates with heteroatom nucleophiles; preparation of P-chiral binol phosphinates and related compounds

Authors
Au-Yeung, TL Chan, KY Chan, WK Haynes, RK Williams, ID Yeung, LL
Citation
Tl. Au-yeung et al., Reactions of (R-P)- and (S-P)-tert-butylphenylphosphinobromidates and tert-butylphenylthionophosphinochloridates with heteroatom nucleophiles; preparation of P-chiral binol phosphinates and related compounds, TETRAHEDR L, 42(3), 2001, pp. 453-456
Citations number
11
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
42
Issue
3
Year of publication
2001
Pages
453 - 456
Database
ISI
SICI code
0040-4039(20010115)42:3<453:RO(A(A>2.0.ZU;2-X
Abstract
Reaction of (R-P)- and (S-P)-tert-butylphenylphosphinobromidates and tert-b utylphenylthionophosphinochloridates with metallated phenol and BINOL alkox ides, thioalkoxides, amides and enolates leading with clean inversion at ph osphorus to phosphinates, phosphinothiolates and phosphinoamidates, and the corresponding thionophosphorus compounds are described. (C) 2001 Elsevier Science Ltd. All rights reserved.