A rate equation model is applied to analyze surface segregation in InGaAs a
nd related compounds during the growth of these materials by molecular beam
epitaxy (MBE). General trends in segregation are examined as a function of
temperature, the V/III ratio and the type of substrate. It is suggested th
at the principal segregation mechanism is related to a near-equilibrium est
ablished between the volatile group III species on the growth surface and i
n the crystal bulk. In particular, this mechanism results in different mani
festations of surface segregation for InGaAs and GaAlAs. (C) 2000 Elsevier
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