Application of radical cage reactions for studies of the microstructure ofpolymers and composites

Authors
Davydov, EY Vorotnikov, AP Pustoshnyi, VP Pariiskii, GB
Citation
Ey. Davydov et al., Application of radical cage reactions for studies of the microstructure ofpolymers and composites, USP KH, 69(10), 2000, pp. 981-992
Citations number
104
Categorie Soggetti
Chemistry
Journal title
USPEKHI KHIMII
ISSN journal
00421308 → ACNP
Volume
69
Issue
10
Year of publication
2000
Pages
981 - 992
Database
ISI
SICI code
0042-1308(2000)69:10<981:AORCRF>2.0.ZU;2-K
Abstract
The potentialities of radical cage reactions as a tool for the investigatio n of polymer physical structure are considered. The kinetic regularities of reactions of triplet carbenes in the martix-isolated state and in clusters are analysed to reveal the structural features of the cage surroundings. T he possibility of determination of the structural characteristics of filled polymers from kinetic data is discussed.