Formation of methylchloroaluminium alkanethiolates, MeAl(SR)Cl, and dichloroaluminium alkanethiolates, Cl2AlSR, from methylaluminium dichloride and trimethylsilyl alkanethiolates, Me3SiSR
Gg. Hoffmann, Formation of methylchloroaluminium alkanethiolates, MeAl(SR)Cl, and dichloroaluminium alkanethiolates, Cl2AlSR, from methylaluminium dichloride and trimethylsilyl alkanethiolates, Me3SiSR, Z NATURFO B, 55(12), 2000, pp. 1195-1198
Citations number
21
Categorie Soggetti
Chemistry
Journal title
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES
Depending on the reaction conditions methylaluminium dichloride, MeAlCl2, a
nd trimethylsilyl alkanethiolates, Me3SiSR, give dichloroaluminium alkaneth
iolates, Cl2AlSR with R = Me and Et or methylchloroaluminium alkanethiolate
s, MeAl(SR)Cl with R = Me, Et, and i-Pr. The reaction pathways are describe
d and IR and H-1 NMR spectroscopic data are presented.