The pentacoordinate titanium complex [TiCl2(NMe2)(2)(HNMe2)]

Authors
Kirschbaum, K Conrad, O Giolando, DM
Citation
K. Kirschbaum et al., The pentacoordinate titanium complex [TiCl2(NMe2)(2)(HNMe2)], ACT CRYST C, 56, 2000, pp. E541-E541
Citations number
4
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
56
Year of publication
2000
Part
12
Pages
E541 - E541
Database
ISI
SICI code
0108-2701(200012)56:<E541:TPTC[>2.0.ZU;2-6
Abstract
Amido complexes of titanium are useful reagents in a variety of syntheses a nd as precursors for chemical vapour deposition of TiN. The title compound, dichlorobis(dimethylamido)(dimethylamine)titanium(IV), [TiCl2(C2H6N)(2)(C2 H7N)], crystallizes with one molecule in the asymmetric unit. The neutral c omplex shows an unusual fivefold coordination of the titanium centre with a distorted trigonal-bipyramidal geometry and the dimethylamine molecule occ upying an axial position.