Liquid crystals composed of photoactive groups, such as azobenzene, are pro
mising materials for optical switching and image storage applications. On e
xposure to light LC materials commonly undergo an order-to disorder transit
ion. Here, an unusual disorder-to-order transition is presented (the Figure
shows a photo-induced smectic texture surrounded by a nematic phase), and
a photo-controlled nanophase segregation mechanism is invoked to explain it
.