Lnj. Rodriguez et al., Fast magic-angle spinning and double-quantum H-1 solid-state NMR spectroscopy of polyelectrolyte multilayers, ADVAN MATER, 12(24), 2000, pp. 1934
Polyelectrolyte multilayers on silica colloids are investigated here using
a combination of fast magic-angle spinning (MAS) and double-quantum (DQ) so
lid-state H-1 NMR techniques. 2D DQ H-1 NMR spectra of the bulk complex and
the multilayer films (see Figure) are found to be similar, revealing compl
exation between the alternating layers of poly(sodium 4-styrenesulfonate) (
PSS) and poly(diallyldimethylammonium chloride) (PDADMAC).