Fast magic-angle spinning and double-quantum H-1 solid-state NMR spectroscopy of polyelectrolyte multilayers

Citation
Lnj. Rodriguez et al., Fast magic-angle spinning and double-quantum H-1 solid-state NMR spectroscopy of polyelectrolyte multilayers, ADVAN MATER, 12(24), 2000, pp. 1934
Citations number
22
Categorie Soggetti
Multidisciplinary,"Material Science & Engineering
Journal title
ADVANCED MATERIALS
ISSN journal
09359648 → ACNP
Volume
12
Issue
24
Year of publication
2000
Database
ISI
SICI code
0935-9648(200012)12:24<1934:FMSADH>2.0.ZU;2-5
Abstract
Polyelectrolyte multilayers on silica colloids are investigated here using a combination of fast magic-angle spinning (MAS) and double-quantum (DQ) so lid-state H-1 NMR techniques. 2D DQ H-1 NMR spectra of the bulk complex and the multilayer films (see Figure) are found to be similar, revealing compl exation between the alternating layers of poly(sodium 4-styrenesulfonate) ( PSS) and poly(diallyldimethylammonium chloride) (PDADMAC).