The sorption of imidacloprid and pyrimethanil was measured in different soi
ls of southern Europe. Pyrimethanil sorption (Kf=1.2-4.60) was higher than
that of imidacloprid (Kf=0.31-1.99). Sorption was influenced by organic car
bon content and increased with time when the soil was incubated at 25 degre
esC and 35% soil water content. Over a period of 14 days, the distribution
coefficient between solid (soil) and solution phases increased by orders of
magnitude of 2 and 4 respectively, for imidacloprid and pyrimethanil. The
increment is consistent with the degradation rate measured, supporting the
hypothesis of the two sites of sorption. Care should be taken when such val
ues are used to predict pesticide fate in soil, particularly for regulatory
purposes during pesticide registration.