FORMATION OF N2O DURING THE THERMAL-DECOMPOSITION OF AMMONIUM-SALTS (NH4)(A)MXOY (M=V, CR, MO AND W)

Authors
VALMALETTE JC HOURIET R HOFMANN H GAVARRI JR
Citation
Jc. Valmalette et al., FORMATION OF N2O DURING THE THERMAL-DECOMPOSITION OF AMMONIUM-SALTS (NH4)(A)MXOY (M=V, CR, MO AND W), European journal of solid state and inorganic chemistry, 34(4), 1997, pp. 317-329
Citations number
19
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
European journal of solid state and inorganic chemistry → ACNP
ISSN journal
09924361
Volume
34
Issue
4
Year of publication
1997
Pages
317 - 329
Database
ISI
SICI code
0992-4361(1997)34:4<317:FONDTT>2.0.ZU;2-6
Abstract
The pyrolysis of several ammonium metallates (M=V, Cr, Mo and W) has b een investigated using mass spectroscopy and infrared spectroscopy ana lyses of the evolved gases. Besides ammonia and water formation, unusu al redox process leading to formation of nitrous oxide N2O is evidence d providing routes for the preparation of alternative phases of metal oxides of interest for catalytic applications or intercalation compoun ds.