Jl. Gautier et al., PHYSICOCHEMICAL VERSUS ELECTROCHEMICAL PROPERTIES OF THIN CUXMN3-XO4 SPINEL FILMS, European journal of solid state and inorganic chemistry, 34(4), 1997, pp. 367-379
Thin copper-manganese oxide films were prepared on conducting glass us
ing the reactive nebulization technique to carry out a study on the ef
fect of Mn substitution by Cu on their physicochemical and electrocata
lytical properties. The electrocatalytical activity of electrode mater
ials on the oxygen evolution reaction (OER) was found to be simultaneo
usly dependent on the open circuit potential (OCP) and on the pH of ze
ro charge (pHz).