Scaling and crossover to tricriticality in polymer solutions

We propose a scaling description of phase separation of polymer solutions. The scaling incorporates three universal limiting regimes: the Ising limit asymptotically close to the critical point of phase separation, the "ideal gas" limit for the pure solvent phase, and the tricritical limit for the po lymer-rich phase asymptotically close to the theta point. We have also deve loped a phenomenological crossover theory based on the near-tricritical-poi nt Landau expansion renormalized by fluctuations. This theory validates the proposed scaled representation of experimental data and crossover to tricr iticality. (C) 2000 MAIK "Nauka/Interperiodica".