B. Brzezinski et al., CYCLIC LI-BONDED SYSTEM WITH LARGE LI+ POLARIZABILITY DUE TO COLLECTIVE LI+ MOTION IN CALIXARENES - AN FT-IR STUDY(), JOURNAL OF PHYSICAL CHEMISTRY B, 101(28), 1997, pp. 5611-5613
Li+ complexes of OH deprotonated calix[4]arene, caIix[6]arene, and cal
ix[8]arene were prepared. The spectra of these complexes show that wit
h Li+ ions the complex formation is complete. In the 1:4, 1:6, and 1:8
complexes, respectively, the Li+ ions are localized in their Li+ bond
s since only a broad band was found in the FT-IR spectra. In the case
of the corresponding 1:3, 1:5, and 1:7 complexes far-IR continua are o
bserved in the region 380-150 cm(-1). These continua demonstrate that
these Li+-bonded systems show large Li+ polarizability due to collecti
ve Li+ motion. This Li+ polarizability increases with the size of the
Li+-bonded systems.