CYCLIC LI-BONDED SYSTEM WITH LARGE LI+ POLARIZABILITY DUE TO COLLECTIVE LI+ MOTION IN CALIXARENES - AN FT-IR STUDY()

Citation
B. Brzezinski et al., CYCLIC LI-BONDED SYSTEM WITH LARGE LI+ POLARIZABILITY DUE TO COLLECTIVE LI+ MOTION IN CALIXARENES - AN FT-IR STUDY(), JOURNAL OF PHYSICAL CHEMISTRY B, 101(28), 1997, pp. 5611-5613
Citations number
10
Categorie Soggetti
Chemistry Physical
Journal title
JOURNAL OF PHYSICAL CHEMISTRY B
ISSN journal
15206106 → ACNP
Volume
101
Issue
28
Year of publication
1997
Pages
5611 - 5613
Database
ISI
SICI code
1089-5647(1997)101:28<5611:CLSWLL>2.0.ZU;2-6
Abstract
Li+ complexes of OH deprotonated calix[4]arene, caIix[6]arene, and cal ix[8]arene were prepared. The spectra of these complexes show that wit h Li+ ions the complex formation is complete. In the 1:4, 1:6, and 1:8 complexes, respectively, the Li+ ions are localized in their Li+ bond s since only a broad band was found in the FT-IR spectra. In the case of the corresponding 1:3, 1:5, and 1:7 complexes far-IR continua are o bserved in the region 380-150 cm(-1). These continua demonstrate that these Li+-bonded systems show large Li+ polarizability due to collecti ve Li+ motion. This Li+ polarizability increases with the size of the Li+-bonded systems.