Effect of substitutional elements on the hydrogen absorption-desorption properties of Ti3Al compounds

Ternary elements M were substituted into Ti3Al with the aim of reducing the hydrogen desorption temperature of Ti,AIH,. On hydrogenation at room tempe rature, three different states, i.e. amorphous, bce and C14 Laves phases, w ere obtained depending on the alloying elements and their amount. The amorp hous hydrides formed in the alloys substituted with Zr or Hf showed a high hydrogen capacity and high hydrogen desorption temperature. in the case of the bce hydrides, formed in the alloys substituted with V or Cr, the hydrog en capacity was largely reduced, but the hydrogen desorption temperature wa s unchanged or increased. Therefore,V and Cr are the worst substitutional e lements to Ti3Al. On the other hand, the hydrides having C14 Laves structur e formed in the alloys substituted with Mn, Co or Ni showed a reduced hydro gen desorption temperature, although the hydrogen capacity was decreased to same extent. From the present work, Mn, Co and Ni are considered to be eff ective elements for improvement of the hydrogen absorption-desorption prope rties of Ti3Al. (C) 2001 Elsevier Science BN. All rights reserved.