Kinetics and mechanism of the reaction of substituted 4-pyrimidine carboxylic acids with diazodiphenylmethane in dimethylformamide

Authors
Jovanovic, B Juranic, I Misic-Vukovic, M Brkic, D Vitnik, Z
Citation
B. Jovanovic et al., Kinetics and mechanism of the reaction of substituted 4-pyrimidine carboxylic acids with diazodiphenylmethane in dimethylformamide, J CHEM R-S, (11), 2000, pp. 506-507
Citations number
12
Categorie Soggetti
Chemistry
Journal title
JOURNAL OF CHEMICAL RESEARCH-S
ISSN journal
03082342 → ACNP
Issue
11
Year of publication
2000
Pages
506 - 507
Database
ISI
SICI code
0308-2342(200011):11<506:KAMOTR>2.0.ZU;2-D
Abstract
Correlation of the data for the reaction of 11 substituted 4-pyrimidine car boxylic acids with diazodiphenylmethane (DDM) in dimethylformamide (DMF) wi th calculated atomic charges on the carboxylic group showed that the reacti on in this solvent may proceed via a concerted transition state.