Cyclic voltammetric studies of alumina supported monometallic Pt and bimetallic Pt-Sn catalysts using carbon paste electrodes

The present work relates to the cyclic voltammetric studies of alumina supp orted monometallic Pt and bimetallic Pt-Sn catalysts using solid carbon pas te electrodes. The cyclic voltammetric data of the solid catalysts, which w ere reproducible, were in agreement with those of electro-deposited Pt and Pt-Sn electrode systems. The reversibility of the II-adsorption-desorption system in representative 0.3 Pt-Al2O3 monometallic catalyst was confirmed b y the difference between the anodic and cathodic peak potentials. The unit ratio of the cathodic to anodic peak currents observed, indicated the equal ity of the transfer coefficient in the kinetics for the respective processe s. The O-2-adsorption-desorption reaction was found to be irreversible as e xpected. The lower area of the curve for H-adsorption-desorption in the cas e of bimetallic catalysts gives an indication for the formation of alloys. The use of a carbon paste electrode in studying the cyclic voltammetric beh avior of heterogenous catalysts yielded qualitative information about the a ctivity of the catalysts. Good correlations were found between cyclic volta mmetric parameters and activity results in both monometallic and bimetallic catalysts. (C) 2000 Elsevier Science B.V. All rights reserved.