The effect of the thermal treatment of silica-based glasses and glass fiber
s on their Rayleigh scattering is investigated experimentally. The Rayleigh
scattering coefficients of bulk glasses are found to be increased 5-10% by
heating them to 1800 degreesC because the density fluctuation is in propor
tion to their fictive temperature. Based on these results, we propose a met
hod for reducing the Rayleigh scattering losses of silica-based optical fib
ers by drawing them slow ly at low temperatures. We used this method to obt
ain a GeO2 doped silica core single-mode fiber with a minimum loss of 0.16
dB/km at 1.55 mum, As a result, we confirmed that the reduction in the fict
ive temperature of silica-based glasses and glass fibers reduces their Rayl
eigh scattering.