The concentration of NaCl solution containing natural organic matter by mem
brane distillation (MD) has been performed. The salt solution produced duri
ng animal intestines processing was used as a feed. The presence of organic
compounds in the feed caused the fouling of MD membranes. The experiments
were performed with polypropylene capillary membranes. A rapid flux decline
caused by the deposition of organic matter on the membrane surface has bee
n observed. The morphology and composition of the fouling layer was studied
using scanning electron microscopy (SEM) coupled with energy dispersion sp
ectrometry (EDS) and Fourier transform infrared with diffuse reflectance sp
ectroscopy (FTIR-DRS). Protein and sodium chloride constituted the major co
mponents of the gel layer. Rinsing of the MD module with a 2 wt.% citric ac
id solution removed a part of the fouling layer. Boiling of spent NaCl solu
tion followed by filtration resulted in the separation of the organic matte
r in the form of a deposit. This enabled a significant reduction in the occ
urrence of fouling phenomenon. (C) 2001 Elsevier Science B.V. All rights re
served.