By combining the concepts of the in-situ composite and hybrid composit
e, a concept of in-situ hybrid composites has been put forward. A comp
osite structure of polyethersulfone reinforced by carbon fibres (CF) a
nd thermotropic liquid crystalline polymer (TLCP) fibrils has been for
med in injection-moulded bars by matching the characteristics and proc
essing conditions of the TLCP and the matrix resin. These TLCP fibrils
with large intrinsic aspect ratios are generated in-situ in the melt
of the resin matrix during the processing of the ternary blends. This
technique uses TLCPs to decrease the viscosity of the whole blend syst
ems and to minimize the CF breakage as well. The improved processabili
ty is especially beneficial for the processing of advanced engineering
plastics. This technique, forming reinforcements at two orders of mag
nitude in the resultant composites, utilizes these two reinforcements
to balance the enhanced mechanical properties of the hybrid composites
. (C) 1997 Elsevier Science Ltd.