M. Hori et M. Toki, Electro-optical properties of inorganic oxide/liquid crystal composite film by the sol-gel process, J SOL-GEL S, 19(1-3), 2000, pp. 349-352
The Electro-optical properties of a composite ceramic/liquid crystal membra
ne, with the dispersed liquid crystals (LCs) in the high dielectric constan
t inorganic oxides, were investigated. The composite membranes having bicon
tinuous micron structure of matrices and LCs were made by the sol-gel proce
ss via the syntheses of multicomponent sols using tetra-n-butyltitanate, ba
rium diethoxyethoxide, methyltriethoxsilane and polyethylene glycol (PEG) f
or phase separation. The switching behaviors of the composite films have be
en observed by applying AC voltages at 1 kHz. It was also confirmed that th
e driving voltage of the composite film depended on the composition of the
inorganic oxide matrix. The composite films of high dielectric constant wer
e driven at an electric field under 10 kV/cm, much less than that of existi
ng PDLC.