Investigating the effects of guest-host interactions on the properties of anion-exchanged Mg-Al hydrotalcites

A starting [Mg-Al-Cl] LDH, prepared by coprecipitation, was further anion-e xchanged to incorporate a variety of anions in the interlayer domain: (Fe(C N)(6))(3-), (P2O7)(4-), (V2O7)(4-), (CrO4)(2-), and (Cr2O7)(2-). The result ing materials were fully characterized using classical techniques like XRPD , FTIR, TGA/DTA, and BET, and their structural modifications studied as a f unction of calcination temperatures. Under mild calcination, only the oxo-a nions were shown to interact strongly with the host matrix. This resulted i n a systematic shrinkage of the interlamellar domain, with a negative impac t on the surface properties. However, intercalation of oxo-anions proved to be beneficial to thermal stability, the lamellar structure being maintaine d up to 400 degreesC in the case of the dichromate intercalated [Mg-Al]. A thorough analysis of the FTIR spectra, revealing an evolution in the symmet ry of some oxo-anions, confirmed the occurrence of a grafting process. Furt hermore, the permanent character of the pillars was evidenced through unsuc cessful rehydration and back-exchange reactions. (C) 2000 Academic Press.