Synthesis and structure of Sb5PO10 a new phosphate of antimony(III)

Authors
Adair, BA Cheetham, AK
Citation
Ba. Adair et Ak. Cheetham, Synthesis and structure of Sb5PO10 a new phosphate of antimony(III), J SOL ST CH, 155(2), 2000, pp. 451-454
Citations number
31
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
JOURNAL OF SOLID STATE CHEMISTRY
ISSN journal
00224596 → ACNP
Volume
155
Issue
2
Year of publication
2000
Pages
451 - 454
Database
ISI
SICI code
0022-4596(200012)155:2<451:SASOSA>2.0.ZU;2-2
Abstract
The antimony(III) phosphate, Sb5PO10, is a framework structure built from v ertex-sharing tetrahedral (SbO3E)-O-III and trigonal bipyramidal (SbO4E)-O- III moieties (E = lone pair) and (PO4)-O-V tetrahedral units; orthorhombic, space group P2(1)2(1)2(1) (No. 19), a = 6,8373(5), b = 7,0932(5), c = 19.8 730(15) Angstrom, V = 963.81(12) Angstrom (3), Z = 8. The structure, determ ined by single crystal X-ray diffraction, is based on alternating layers of antimony oxide and antimony phosphate. (C) 2000 Academic Press.