On the basis of DTA analyses, three (1-x)TeO2-xLiCl (s = 0.3, 0.35 and 0.4
mol) glasses doped with 0.005 mol of Tm2O3 were crystallized in the vicinit
y of 400 degreesC. X-ray investigations for samples heated to 425 degreesC
(above the peak crystallization temperature) followed by quenching in air,
revealed the presence of the paratellurite (TeO2) as the only crystallizing
phase in all glass compositions. SEM investigations revealed that the para
tellurite crystals formed in these glasses as a result of surface crystalli
zation were trigonal in shape, between 40 and 50 mum in length, 7 and 15 mu
m in width and 5 and 9 Cim in depth. DTA analyses were carried out on the 0
.7TeO(2)-0.3LiCl glass at different heating rates and an activation energy
value of 238 kJ/mol for surface crystallization was determined graphically
from a Kissinger-type: plot using the analysis of Matusita and Sakka (Matus
ita, K. and Sakka, S., Kinetic study on crystallization of glass by differe
ntial thermal analysis - criterion on application of Kissinger plot. (C) 20
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