H. Kawaura et al., New surface treatment using shot blast for improving oxidation resistance of TiAl-base alloys, J JPN METAL, 64(11), 2000, pp. 1027-1032
A new surface treatment by shot blasts using WO3 powder has been developed.
This has been most effective in improving the cyclic oxidation resistance
of TiAl-base alloy in air and in a diesel engine exhaust gas atmosphere up
to 1223 K. This effect is attributed to the formation of an Al2O3 layer in
an oxidizing atmosphere. The above layer is supposed to be formed as follow
s: Since the WO3 powder is shot repeatedly during the surface treatment, a
WO3 layer adhering to the substrate is formed on the surface. This layer ca
uses the preferential oxidation of aluminum at the early stage of oxidation
, resulting in the formation of a sound and continuous Al2O3 layer. The dev
eloped surface treatment gives the same oxidation resistance as that of nic
kel-base superalloy Inconel 713C up to 1223 K, and is applicable to complex
-shape parts with as-cast skin surfaces, such as turbocharger wheels.