An original experimental technique for simultaneous electrical conductivity
and thermo-e.m.f. measurements in a wide temperature range (up to 2000 K)
under high pressures (up to 50 MPa) has been developed. Special ceramic mea
suring cells were designed and constructed for investigation of chemically
aggressive liquid semiconductors. Different sources of errors connected wit
h convective flows, jamming signals, systematic deviation of measuring devi
ces and especially diffusion of the liquid sample into the body of the cera
mic are analysed and method of elimination are proposed. New results for so
me liquid metal-chalcogen alloys in comparison with those obtained earlier
illustrate advantages of the proposed method.