REACTIONS OF LASER-ABLATED ALUMINUM ATOMS WITH AMMONIA - INFRARED-SPECTRA OF HALNH2, ALNH2, AND HALNH IN SOLID ARGON

Authors
LANZISERA DV ANDREWS L
Citation
Dv. Lanzisera et L. Andrews, REACTIONS OF LASER-ABLATED ALUMINUM ATOMS WITH AMMONIA - INFRARED-SPECTRA OF HALNH2, ALNH2, AND HALNH IN SOLID ARGON, The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory, 101(28), 1997, pp. 5082-5089
Citations number
30
Categorie Soggetti
Chemistry Physical
Journal title
The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory → ACNP
ISSN journal
10895639
Volume
101
Issue
28
Year of publication
1997
Pages
5082 - 5089
Database
ISI
SICI code
1089-5639(1997)101:28<5082:ROLAAW>2.0.ZU;2-C
Abstract
Pulsed laser-ablated Al atoms react with NH3 to give two major product s, HAlNH2 and AlNH2, which are trapped in solid argon and identified f rom infrared spectra through isotopic substitution (N-15, D) and MP2 c alculations of product structures and isotopic frequencies. The bent H AlNH molecule was a minor product.