We present a detailed study of the morphological features of 22 rich galaxy
clusters. Our sample is constructed from a cross-correlation of optical (A
bell+APM) data with X-ray (0.1-2.4 keV) ROSAT pointed observations. We syst
ematically compare cluster images and morphological parameters in an attemp
t to reliably identify possible substructure in both optical and the X-ray
images. To this end, we compute various moments of the optical and X-ray su
rface-brightness distribution such as the ellipticities, centre-of-mass shi
fts and ellipsoidal orientations. We assess the significance of our results
using Monte Carlo simulations. We find significant correlations between th
e optical and X-ray morphological parameters, indicating that in both parts
of the spectrum it is possible to identify correctly the dynamical state o
f a cluster. Most of our clusters (17/22) have a good one-to-one correspond
ence between the optical and the X-ray images, and about 10 appear to have
strong indications of substructure. This corresponds to a minimum percentag
e of order similar to 45 per cent, which is in very good accordance with ot
her similar analyses. Finally, five out of 22 systems (similar to 22 per ce
nt) seem to have distinct subclumps in the optical which are not verified i
n the X-ray images, and thus are suspect of being due to optical projection
effects. These results will serve as a useful guide in interpreting subseq
uent analyses of large optical cluster catalogues.