Complexation of cylic and acyclic dienes, carrying a (1S)-(+)-ketopinoxy as
the chiral auxiliary, with nonacarbonyldiiron proceeds in a completely dia
stereoselective fashion to afford diene-iron complexes in moderate yields.
When (1R)-(-)-ketopinoxy was used as the chiral auxiliary, the opposite ena
ntioisomeric complexes are isolated as a single diastereomer in comparable
yield and specific rotation in each case. The stereochemistry of chiral cyc
lic and acyclic diene-iron complexes is determined by single-crystal X-ray
methods.