Mechanical properties and transmission electron microscopy studies of singl
e crystals of gamma -Ti-54.5 at.% Al of various orientations for which ordi
nary slip occurs show that at the temperature T-p of the peak stress of the
yield stress anomaly (YSA) the critical resolved shear stresses (CRSSs) fo
r ordinary slip on {110) and {111} are comparable, and that above T-p, the
CRSS on {110) decreases rapidly with increasing temperature. The glide loop
s on (110) are elongated along the [001] direction, indicating the low mobi
lity of edge dislocations. Below T-p, slip occurs on {111} and the screw di
slocations are much less mobile than the edge dislocations, forming effecti
vely long locks. Further slip (unlocking) is thought to occur by the genera
tion and glide of edge superkinks along the screw direction. In the region
of the YSA, before unlocking occurs, the screws bow out, mainly on {111} an
d partly on {110), the latter resulting in relatively immobile jogs which a
ct as obstacles to slip on {111} and to the motion of the superkinks. Bowin
g on {110) has been observed in this work and by others. The YSA is conside
red to be due to increasing amounts of bowing on {110) with increasing temp
erature, and thus the formation of larger jogs on {110) in dislocations gli
ding on {111}. The driving forces for this mechanism are attributed to the
screw dislocations having a minimum line tension on {110) and, except for a
lloys with less than about 54 at.% Al, to a lower resistance from the effec
t of short-range order associated with the Al5Ti3 phase for slip on {110) t
han on {111}. The large activation volumes observed below T-p are thought t
o be associated with mechanisms controlling the generation and motion of ed
ge superkinks, involving thermally activated processes including climb at s
mall jogs, and various mechanisms of cross-slip. Above T-p the rate-control
ling process is considered to be thermally activated or climb-controlled gl
ide of edge dislocations on {110) planes. The model for the YSA is discusse
d in the light of results from other studies.